Palladium is a relatively inexpensive transition metal when compared with rhodium, and is thus more attractive for industrial applications. However, the development of Pd(II) catalyst systems for the asymmetric addition of arylboronic acids to electron-deficient olefins was not as widely developed as Rh(I) catalytic systems until recent years. Several new and efficient Pd(II) catalyst systems have been developed in this decade, enabling the asymmetric additions of arylboronic acids to different types of substrates. This brief review summarizes and discusses recent works related to the Pd(II)-catalyzed asymmetric addition of arylboronic acids to electron-deficient olefins.

与铑相比，钯是一种相对便宜的过渡金属，因此对于工业应用更具吸引力。但是，直到最近几年，用于将芳基硼酸不对称加成到缺电子烯烃中的Pd（II）催化剂体系的开发尚未像Rh（I）催化体系那样广泛地开发。在此十年中，已经开发了几种新型的高效Pd（II）催化剂体系，能够将芳基硼酸不对称地添加到不同类型的底物中。这篇简短的综述总结和讨论了有关Pd（II）催化芳基硼酸不对称加成到缺电子烯烃中的最新工作。