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Modeling the rheological properties of currant paste as a function of plasticizers concentration, storage temperature and time and process temperature
Food Research International ( IF 8.1 ) Pub Date : 2018-10-09 , DOI: 10.1016/j.foodres.2018.10.025
Eirini K. Nikolidaki , Ioanna Mandala , Nikolaos P. Zogzas , Vaios T. Karathanos

The steady and dynamic shear rheological properties of currant paste samples as a function of storage temperature (15, 25 and 35 °C) and time (180 days) and plasticizers content (water and/or glycerol) have been evaluated. Apparent viscosity (ηa) has been found to be significantly increased with prolonged storage, implying possible structural changes, and decreased with the increase in storage temperature and the addition of water or/and glycerol. Flow behavior index and consistency index were determined by fitting the resulting experimental data to a power law equation with high values of correlation coefficients (R2 ≥ 0.912). Furthermore, the combined effect of storage temperature, time and plasticizers concentration on the apparent viscosity was described adequately by a proposed empirical model, with low standard relative errors (SRE ≤ 0.011). Additionally, the viscoelastic properties were significantly affected by all evaluated parameters in the same way as in apparent viscosity while both moduli (G′ and G″) were modeled sufficiently (R2 ≥ 0.884) as power functions of oscillatory frequency. The heat treatment (heating from 25 to 100 °C and cooling back with a rate of 10 °C/min) applied has proved sufficient to reverse the observed storage effects. Moreover, the modified Cox-Merz rule was satisfactorily applied to describe the correlation between the apparent viscosity and the complex viscosity.



中文翻译:

建立与增塑剂浓度,储存温度以及时间和加工温度有关的醋栗糊的流变特性模型

评估了醋栗糊样品的稳态和动态剪切流变性质,其与储存温度(15、25和35℃)和时间(180天)以及增塑剂含量(水和/或甘油)的关系。表观粘度(η一个)已被发现与长期储存地显著增加,这暗示可能的结构变化,以及与存储装置中温度的上升和添加水和/或甘油降低。通过将所得实验数据拟合到具有高相关系数值(R 2 ≥0.912)。此外,通过建议的经验模型充分描述了存储温度,时间和增塑剂浓度对表观粘度的综合影响,且标准相对误差较低(SRE≤0.011)。此外,粘弹性性能显著影响以相同的方式评价所有参数,如表观粘度而两个模量(G'和G“)充分建模(R 2  ≥0.884)作为振荡频率的功率的功能。事实证明,进行热处理(从25到100°C加热并以10°C / min的速度冷却)可以逆转所观察到的存储效果。此外,满意地应用了改进的Cox-Merz规则来描述表观粘度和复数粘度之间的相关性。

更新日期:2018-10-09
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