Tetrahedron Letters ( IF 1.8 ) Pub Date : 2018-10-08 , DOI: 10.1016/j.tetlet.2018.10.011 Limei Tian , Jia Xue , Zheng-yin Yang
A simple Al3+ receptor, 2-hydroxyquinoline-3-aldehyde-(benzoyl)hydrazone (L), has been synthesized by condensing 2-hydroxyquinoline-3-aldehyde with benzoic hydrazide. L displayed a high selectivity and pronounced fluorescence enhancement for Al3+ over other common cations in water. Moreover, based on the Job’s plot, ESI-MS spectrometry, it could be considered that L and Al3+ were coordinated with a 1:1 ratio. In addition, the detection limit of L for sensing Al3+ was calculated to be 7.21 × 10−8 M, which was lower than the acceptable limit of Al3+ level in drinking water defined by World Health Organization (WHO) (1.85 × 10−6 M). These results indicated that this chemical sensor L could be used as a serviceable molecular probe for practical applications.
中文翻译:
一种简单的喹啉衍生物作为荧光探针,对水溶液中的Al 3+具有高灵敏度和选择性
通过将2-羟基喹啉-3-醛与苯甲酰肼缩合,合成了一种简单的Al 3+受体2-羟基喹啉-3-醛-(苯甲酰基)hydr(L)。L在水中显示出对Al 3+的高选择性和明显的荧光增强。此外,根据乔布斯图,ESI-MS光谱法,可以认为L和Al 3+的配比为1:1。另外,用于感测Al 3+的L的检测极限被计算为7.21×10 -8 M,低于Al 3+的可接受极限。世界卫生组织(WHO)定义的饮用水中的水含量(1.85×10 -6 M)。这些结果表明,该化学传感器L可以用作实际应用中的有用的分子探针。