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Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity
Journal of the American Chemical Society ( IF 15.0 ) Pub Date : 2018-10-08 , DOI: 10.1021/jacs.8b08770
Arnaud Chaix 1 , Georges Mouchaham 2 , Aleksander Shkurenko 2 , Phuong Hoang 1 , Basem Moosa 1 , Prashant M. Bhatt 2 , Karim Adil 2 , Khaled N. Salama 3 , Mohamed Eddaoudi 2 , Niveen M. Khashab 1
Affiliation  

Here we introduce for the first time a metal-free trianglamine-based supramolecular organic framework, T-SOF-1, with permanent intrinsic porosity and high affinity to CO2. The capability of tuning the pore aperture dimensions is also demonstrated by molecular guest encapsulation to afford excellent CO2/CH4 separation for natural gas upgrading.

中文翻译:

具有永久固有孔隙率和可调选择性的基于三角胺的超分子有机框架

在这里,我们首次介绍了一种基于无金属三角胺的超分子有机骨架 T-SOF-1,它具有永久的固有孔隙率和对 CO2 的高亲和力。分子客体封装也证明了调节孔径尺寸的能力为天然气提质提供了出色的 CO2/CH4 分离。
更新日期:2018-10-08
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