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Side chain engineering for the regulation of quinoxaline based D-A copolymers
Dyes and Pigments ( IF 4.5 ) Pub Date : 2018-10-08 , DOI: 10.1016/j.dyepig.2018.10.010
Yunqiang Zhang , Can Zhu , Jun Yuan , Hongjian Peng , Yingping Zou , Yongfang Li

In the paper, the quinoxaline(QX) polymer donor material with 4-methoxythiophene as the side chain was designed and synthesized by side chain modification engineering and named as PBMOQX. It has good solubility in common organic solvents. In addition, a series of characterizations of the conjugated polymer were performed. There is a good spectral absorption at 300–700 nm with an electrochemical bandgap of 1.83 eV and an optical bandgap of 1.63 eV. With 0.5% of 1, 8-diiodooctane as an additive in a mixing ratio of PBMOQX: PC71BM = 1:1.5, the device achieves a power conversion efficiencies (PCE) of 6.94%. These studies indicate that the novel copolymer PBMOQX is a promising photovoltaic donor material for high efficiency polymer solar cells (PSCs).



中文翻译:

侧链工程用于调节喹喔啉基DA共聚物

本文通过侧链修饰工程设计合成了以4-甲氧基噻吩为侧链的喹喔啉(QX)聚合物供体材料,命名为PBMOQX。在普通有机溶剂中具有良好的溶解性。另外,对共轭聚合物进行了一系列表征。在300-700 nm处有良好的光谱吸收,电化学带隙为1.83 eV,光学带隙为1.63 eV。在PBMOQX:PC 71 BM = 1:1.5的混合比下,以0.5%的1,8-二碘辛烷作为添加剂,该器件的功率转换效率(PCE)为6.94%。这些研究表明,新型共聚物PBMOQX是用于高效聚合物太阳能电池(PSC)的有前途的光伏供体材料。

更新日期:2018-10-08
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