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Visible-light initiated aerobic oxidations: a critical review
Green Chemistry ( IF 9.8 ) Pub Date : 2018-10-08 , DOI: 10.1039/c8gc02382d
Xu Zhang 1, 2, 3, 4, 5 , K. P. Rakesh 1, 2, 3, 4, 5 , L. Ravindar 1, 2, 3, 4, 5 , Hua-Li Qin 1, 2, 3, 4, 5
Affiliation  

The development of new and highly efficient strategies for the rapid construction of complicated molecular structures has huge implications and remains a preeminent goal in present day synthetic chemistry. In the past ten years, visible light promoted aerobic oxidations have been emerging as one of the fastest growing fields in organic chemistry because of their low cost, easy availability and environmental friendliness. This review describes and highlights the scope and limitations, recent research progress in novel methodology development, and applications in organic synthesis, as well as the mechanisms of these visible light promoted aerobic oxidation reactions. The discussion contains several sections based on the following reaction types: (1) alcohols to aldehydes; (2) amines to nitriles; (3) methylarenes to aldehydes; (4) boronic acids to phenols; (5) formation of carbonyl compounds or ketones; (6) β-keto sulfones; (7) sulfoxides; (8) amine to amide; and (9) some other reactions.

中文翻译:

可见光引发的好氧氧化:一项重要的审查。

快速构建复杂分子结构的新高效策略的发展具有巨大的意义,并且仍然是当今合成化学的主要目标。在过去的十年中,可见光促进的好氧氧化已经成为有机化学中增长最快的领域之一,因为它们的成本低,易于获得且对环境友好。这篇综述描述并强调了其范围和局限性,新方法学开发的最新研究进展以及在有机合成中的应用,以及这些可见光促进需氧氧化反应的机理。讨论包括基于以下反应类型的几个部分:(1)醇转化为醛;(2)胺转化为腈;(3)甲基芳烃为醛;(4)硼酸为苯酚;(5)形成羰基化合物或酮;(6)β-酮砜;(7)亚砜;(8)胺转化为酰胺;(9)其他一些反应。
更新日期:2018-10-30
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