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Effects of lipids on the water sorption, glass transition and structural strength of carbohydrate-protein systems
Food Research International ( IF 8.1 ) Pub Date : 2018-10-03 , DOI: 10.1016/j.foodres.2018.10.008
V.A. Maidannyk , A.S.L. Lim , M.A.E. Auty , Y.H. Roos

Encapsulant systems are gaining wide practical interest due to their functional and nutritional properties. This paper was focusing on understanding structural relaxations in that systems near glass transition temperature. Freeze-dried trehalose-whey protein isolate-sunflower oil systems with various ratios of the last were used as a carbohydrate-protein-lipid food model. The Guggenheim-Anderson-de Boer (GAB) water sorption relationship was used as a tool to model water sorption isotherms. The glass transition temperature was obtained by differential scanning calorimetry (DSC). Structural α-relaxation temperatures were measured by dynamical mechanical analyses (DMA), dielectric analysis (DEA) and combined to cover a broad range for strength assessment. The microstructure was characterized by optical light microscopy, confocal laser scanning microscopy and scanning electron microscopy. The C1 and C2 constants for Williams-Landel-Ferry (WLF) equation and structural strength parameter were calculated for each system. The effect of sunflower oil and water contents on strength of carbohydrate-protein system was analyzed. Strength shows decreasing with increasing of lipid concentration in the mixtures and more complex dependence on the water content in a system.



中文翻译:

脂质对碳水化合物-蛋白质系统的水分吸收,玻璃化转变和结构强度的影响

密封剂系统由于其功能和营养特性而获得了广泛的实用兴趣。本文的重点是理解在接近玻璃化转变温度的系统中的结构弛豫。冷冻干燥的海藻糖-乳清蛋白分离物-葵花籽油系统具有不同的最后比率,用作碳水化合物-蛋白-脂质食物模型。Guggenheim-Anderson-de Boer(GAB)的吸水率关系用作模拟吸水等温线的工具。通过差示扫描量热法(DSC)获得玻璃化转变温度。结构α松弛温度通过动态力学分析(DMA),介电分析(DEA)进行测量,并结合在一起以涵盖广泛的强度评估范围。通过光学显微镜对显微组织进行了表征,共聚焦激光扫描显微镜和扫描电子显微镜。C为每个系统计算了Williams-Landel-Ferry(WLF)方程的1和C 2常数以及结构强度参数。分析了向日葵油和水分含量对碳水化合物-蛋白质系统强度的影响。强度显示出随着混合物中脂质浓度的增加而降低,并且对系统中水含量的依赖性更加复杂。

更新日期:2018-10-04
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