This account summarizes Pd(0)-catalyzed Mo(CO)6-mediated gas-free carbonylative reactions published in the period October 2011 to May 2018. Presented reactions include inter- and intramolecular carbonylations, carbonylative cross-couplings, and carbonylative multicomponent reactions using Mo(CO)6 as a solid source of CO. The presented methodologies were developed mainly for small-scale applications, avoiding the problematic use of gaseous CO in a standard laboratory. In most cases, the reported Mo(CO)6-mediated carbonylations were conducted in sealed vials or by using two-chamber solutions. 1 Introduction 2 Recent Developments 2.1 New CO Sources 2.2 Two-Chamber System for ex Situ CO Generation 2.3 Multicomponent Carbonylations 3 Carbonylations with N and O Nucleophiles 4 Carbonylative Cross-Coupling Reactions with Organometallics 5 Carbonylative Cascade Reactions 6 Carbonylative Cascade, Multistep Reactions 7 Summary and Outlook

中文翻译：

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钯催化的六羰基钼介导的无气体羰基化反应

该帐户总结了 2011 年 10 月至 2018 年 5 月期间发表的 Pd(0) 催化的 Mo(CO)6 介导的无气体羰基化反应。提出的反应包括分子间和分子内羰基化、羰基化交叉偶联和羰基化多组分反应，使用Mo(CO)6 作为 CO 的固体来源。所提出的方法主要是为小规模应用而开发的，避免了在标准实验室中使用气态 CO 的问题。在大多数情况下，报道的 Mo(CO)6 介导的羰基化是在密封小瓶中或使用两室溶液进行的。1 介绍 2 最新发展 2.1 新的 CO 源 2.2 异地 CO 生成 2 的两室系统。