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Addressing the viscosity challenge: ultrafast, stable-flow synthesis of zeolites with an emulsion method†
Reaction Chemistry & Engineering ( IF 3.9 ) Pub Date : 2018-10-03 00:00:00 , DOI: 10.1039/c8re00139a
Jie Zhu 1, 2, 3, 4 , Zhendong Liu 1, 2, 3, 4 , Yasuo Yonezawa 1, 2, 3, 4 , Kazuto Honda 1, 2, 3, 4 , Satoshi Okada 4, 5, 6, 7, 8 , Shigeru Deguchi 4, 5, 6, 7, 8 , Tatsuya Okubo 1, 2, 3, 4 , Toru Wakihara 1, 2, 3, 4
Affiliation  

The sharp viscosity increase taking place in the zeolite formation renders continuous flow synthesis extremely challenging. We herein show that the emulsion system together with a Teflon-lined pipe reactor offers a unique opportunity to address the viscosity issue, allowing the zeolite products to smoothly flow out of the reactor in the form of a suspension. The emulsion-based, continuous flow synthesis of three important zeolites – ERI, *BEA and CHA – was achieved, demonstrating this method to be a general approach.

中文翻译:

解决粘度挑战:采用乳液法超快,稳定流动地合成沸石

沸石地层中粘度的急剧增加使得连续流合成极具挑战性。我们在此表明​​,乳液体系与衬有特氟隆的管式反应器一起提供了解决粘度问题的独特机会,从而允许沸石产品以悬浮液的形式平稳地流出反应器。实现了三种重要沸石(ERI,* BEA和CHA)的基于乳液的连续流动合成,证明了该方法是一种通用方法。
更新日期:2018-10-03
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