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The H2S Dimer is Hydrogen‐Bonded: Direct Confirmation from Microwave Spectroscopy
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2018-10-19 , DOI: 10.1002/anie.201808162
Arijit Das 1 , Pankaj K. Mandal 2 , Frank J. Lovas 3 , Chris Medcraft 4 , Nicholas R. Walker 5 , Elangannan Arunan 1
Affiliation  

Ice and solid H2S look as different as pears and oranges, leading Pauling to conclude that H2O has hydrogen bonds and H2S has van der Waals interactions. Now it is shown that the H2S dimer, like the H2O dimer, is indeed hydrogen‐bonded.
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中文翻译:

H2S二聚体是氢键结合的:通过微波光谱法直接确认

冰和固体H 2 S看起来与梨和橘子不同,从而使鲍林得出结论,H 2 O具有氢键,而H 2 S具有范德华相互作用。现在表明,H 2 S二聚体与H 2 O二聚体确实是氢键结合的。
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更新日期:2018-10-19
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