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Hydrothermal synthesis of MCM-49 zeolite with cyclohexylamine template
Microporous and Mesoporous Materials ( IF 5.2 ) Pub Date : 2018-09-29 , DOI: 10.1016/j.micromeso.2018.09.034
Ji Qian , Guang Xiong , Jiaxu Liu , Chunyan Liu , Hongchen Guo

Hexamethyleneimine (HMI) is used as the structure-directing agent (SDA) in the conventional synthesis method of MCM-49 zeolite. Cyclohexanine (CA) is less toxic and cheaper than HMI. Hence, in this paper, MCM-49 zeolite was successfully synthesized by using CA as a sole SDA with the aid of seeds. Both the seed and template CA are indispensable for the synthesis of MCM-49 zeolite. The optimum synthesis conditions were obtained. The range of the SiO2/Al2O3 ratio of the initial gel was broadened to 70. The synthesis of MCM-49 followed the liquid-phase crystallization mechanism. The MCM-49 zeolites synthesized by using CA and conventional template hexamethyleneimine (HMI) exhibit similar intrinsic properties, such as morphology, acidity, BET surface area, SiO2/Al2O3, and so on. The MCM-49(CA) exhibite good catalytic activity and product distribution in alkylation of benzene with methanol.



中文翻译:

环己胺模板水热合成MCM-49分子筛

在传统的MCM-49沸石合成方法中,六亚甲基亚胺(HMI)被用作结构导向剂(SDA)。环己氨酸(CA)的毒性比HMI低,且价格便宜。因此,在本文中,通过将CA用作种子的唯一SDA,成功地合成了MCM-49沸石。种子和模板CA都是合成MCM-49沸石必不可少的。获得了最佳的合成条件。初始凝胶的SiO 2 / Al 2 O 3比范围扩大到70。MCM-49的合成遵循液相结晶机理。使用CA和常规模板六亚甲基亚胺(HMI)合成的MCM-49沸石具有相似的固有特性,例如形态,酸度,BET表面积,SiO2 / Al 2 O 3,依此类推。MCM-49(CA)在苯与甲醇的烷基化反应中表现出良好的催化活性和产物分布。

更新日期:2018-09-29
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