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The Synthesis of Benzofulvenes through Palladium‐Catalyzed Sequential Three‐Component Reactions
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2018-10-22 , DOI: 10.1002/adsc.201801141 Bo Zhou 1 , Zhuo Wu 1 , Weixin Qi 1 , Xueliang Sun 1 , Yanghui Zhang 1
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2018-10-22 , DOI: 10.1002/adsc.201801141 Bo Zhou 1 , Zhuo Wu 1 , Weixin Qi 1 , Xueliang Sun 1 , Yanghui Zhang 1
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An approach for the synthesis of benzofulvenes has been developed through palladium‐catalyzed sequential three‐component reactions. The reactions likely involve C,C‐palladacycles as the key intermediates. The palladacycles are generated through cascade reactions of aryl halides and alkynes, and then reacted with CH2Br2 to form benzofulvenes as the final products.
中文翻译:
钯催化顺序三组分反应合成苯并富烯
通过钯催化的连续三组分反应,已经开发出一种苯并富烯的合成方法。反应可能涉及C,C- palladacycles作为关键中间体。Palladacycles是通过芳基卤化物和炔烃的级联反应生成的,然后与CH 2 Br 2反应形成苯并富勒烯作为最终产物。
更新日期:2018-10-22
中文翻译:
钯催化顺序三组分反应合成苯并富烯
通过钯催化的连续三组分反应,已经开发出一种苯并富烯的合成方法。反应可能涉及C,C- palladacycles作为关键中间体。Palladacycles是通过芳基卤化物和炔烃的级联反应生成的,然后与CH 2 Br 2反应形成苯并富勒烯作为最终产物。