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Size effects of micro-pattern on lithium metal surface on the electrochemical performance of lithium metal secondary batteries
Journal of Power Sources ( IF 9.2 ) Pub Date : 2018-09-24 , DOI: 10.1016/j.jpowsour.2018.09.061
Joonam Park , Dohwan Kim , Dahee Jin , Charudatta Phatak , Kuk Young Cho , Young-Gi Lee , Seungbum Hong , Myung-Hyun Ryou , Yong Min Lee

Two micro-patterns of different sizes (50 and 80 μm) are designed to have equivalent capacities of 1.06 and 2.44 mAh cm−2 by building a computational battery model. After preparing two stamps each possessing a micro-pattern design, the corresponding pattern is properly imprinted on the surface of 100 μm lithium metal, which is confirmed by scanning electron microscopy. When both micro-patterned lithium metals are electrochemically reduced and oxidized up to 1 mAh cm−2 in Li/Li symmetric cells at 1 or 2 mA cm−2, the 80 μm-patterned lithium shows a more stabilized lower overpotential during long-term cycling than the 50 μm-patterned and bare lithium, probably due to the lithium anchoring effect and a larger empty volume in the patterns. Additionally, an overflow of lithium deposits is easily observed in the 50 μm-patterned lithium metal, while the 80 μm-patterned lithium metal holds most of the lithium deposits within the patterns. When both micro-patterned lithium metals are assembled to full cells with a LiNi0·6Co0·2Mn0·2O2 cathode of 2 mAh cm−2, the 80 μm-patterned lithium metal shows much better electrochemical performances with stable plating/stripping behavior within the patterns.



中文翻译:

锂金属表面微细图形的尺寸效应对锂金属二次电池电化学性能的影响

 通过建立计算电池模型,将两个不同大小(50和80μm)的微图案设计为具有1.06和2.44 mAh cm -2的等效容量。在制备两个均具有微图案设计的印模之后,将相应的图案适当地压印在100μm锂金属的表面上,这可通过扫描电子显微镜确认。当两个微图案化的锂金属被电化学还原和氧化高达1毫安厘米-2中对于Li / Li对称细胞以1或2毫安厘米-2,图案为80μm的锂在长期循环过程中显示出比50微米为图案的裸锂更稳定的低电势,这可能是由于锂的锚固效应和图案中较大的空体积所致。另外,在图案为50μm的锂金属中很容易观察到锂沉积物的溢出,而图案为80μm的锂金属则将大部分锂沉积物保留在图案中。当将两种微图案化的锂金属组装成具有2 mAh cm -2的LiNi 0·6 Co 0·2 Mn 0·2 O 2阴极的完整电池时,具有80μm图案化的锂金属表现出更好的电化学性能,且稳定性高图案内的电镀/剥落行为。

更新日期:2018-09-24
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