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Olefin Bifunctionalization: A Visible‐light Photoredox‐catalyzed Aryl Alkoxylation of Olefins
Chemistry - An Asian Journal ( IF 4.1 ) Pub Date : 2018-12-06 , DOI: 10.1002/asia.201801211
Eiji Yamaguchi 1 , Wakako Tanaka 1 , Akichika Itoh 1
Affiliation  

Olefin bifunctionalization is a facile route to obtain complex molecules from abundant and commercially available olefin feedstocks. Visible light together with a catalytic amount of tris(bipyridine)ruthenium salt catalyzes the aryl alkoxylation of styrenes with aryl diazonium salts in alcohol solvents via a photoredox process. The scope of this proposed reaction with respect to various aryl diazonium salts and styrenes has been investigated.

中文翻译:

烯烃双功能化:可见光光氧化还原催化的烯烃芳烷基烷氧基化

烯烃双官能化是从丰富的和可商购的烯烃原料中获得复杂分子的简便途径。可见光与催化量的三(联吡啶)钌盐一起通过光氧化还原工艺在醇溶剂中催化苯乙烯与芳基重氮盐的芳基烷氧基化反应。已经针对各种芳基重氮盐和苯乙烯研究了该拟议反应的范围。
更新日期:2018-12-06
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