A tert-butyl carbazole-modified difluoroboron β-diketonate complex (TCbzB) has been synthesized. Although no traditional gelation group was involved in TCbzB, it could form organogels in the mixed solvents of o-dichlorobenzene/cyclohexane (v/v = 1/5 or 1/2), toluene/cyclohexane (v/v = 1/2) and chlorobenzene/cyclohexane (v/v = 1/2). Interestingly, an orange organogel was obtained in o-dichlorobenzene/cyclohexane (v/v = 1/2) with relatively high polarity and red organogels were gained in the other three mixed solvents with relatively low polarity. TCbzB self-assembled into H-aggregates and J-aggregates in orange and red organogels, respectively, and the corresponding xerogels emitted yellow and red light, respectively, under UV illumination. The red emission of the xerogel-based film could be quenched significantly by gaseous n-propylamine and aniline because of the decomplexation of the difluoroboron β-diketonate complex by n-propylamine and the weak interactions between aniline and boron difluoride units.

中文翻译：

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由非传统π型胶凝剂形成的H和J聚集体，取决于用于检测胺蒸气的溶剂极性

甲叔丁基咔唑改性的difluoroboronβ二酮配合物（TCbzB）已被合成。尽管TCbzB没有涉及传统的凝胶化基团，但是它可以在邻二氯苯/环己烷（v / v = 1/5或1/2），甲苯/环己烷（v / v = 1/2）的混合溶剂中形成有机凝胶。和氯苯/环己烷（v / v = 1/2）。有趣的是，在邻二氯苯/环己烷（v / v = 1/2）中获得了极性相对较高的橙色有机凝胶，而在其他三种极性相对较低的混合溶剂中获得了红色有机凝胶。TCbzB分别在橙色和红色有机凝胶中自组装成H聚集体和J聚集体，相应的干凝胶在紫外线照射下分别发出黄光和红光。基于干凝胶膜的红色发射可以通过显著气态猝灭Ñ丙胺和苯胺因为difluoroboron的解络的β二酮络合物Ñ丙胺和苯胺和二氟化硼单元之间的弱相互作用。