A general approach to the functionalization of aliphatic C–Si bonds in the presence of silver salts and oxidants has been reported. This strategy encompasses a range of valuable C–Si transformations, including the direct conversions of a C–Si bond to C–OCF₃, C–OBz, C–OCOCF₃, C–SCF₃, C–SCN, and C–N₃ bonds. Among them, trifluoromethoxylation of alkylsilanes is reported for the first time. In addition, mechanistic studies indicate that this reaction may proceed through a radical mechanism.

中文翻译：

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银介导的烷基硅烷的氧化功能化†

已经报道了在银盐和氧化剂存在下脂族C-Si键官能化的一般方法。该策略包括一系列有价值的C–Si转换，包括C–Si键直接转换为C–OCF ₃，C–OBz，C–OCOCF ₃，C–SCF ₃，C–SCN和C–N _3个债券。其中，首次报道了烷基硅烷的三氟甲氧基化。另外，机理研究表明该反应可能通过根本机理进行。