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Cerium(IV)‐Promoted Phosphinoylation‐Nitratation of Alkenes
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2018-10-11 , DOI: 10.1002/adsc.201800985
Bin Yang 1 , Shu-Min Hou 1 , Shi-Yu Ding 1 , Xiao-Nan Zhao 1 , Yuan Gao 1 , Xue Wang 1 , Shang-Dong Yang 2
Affiliation  

A Cerium(IV)‐promoted phosphinoylation‐nitratation of alkenes is established under mild conditions. In this process, Ceric ammonium nitrate (CAN) acts as a cheap phosphorus‐radical initiator, as well as a nitrate donor. Various β‐nitrooxyphosphonates are delivered in high yield in a one‐pot manner.

中文翻译:

铈(IV)促进的烯烃的膦酰基化-硝化

在温和条件下建立了铈(IV)促进的膦酰化-硝化的烯烃。在此过程中,硝酸铈铈(CAN)充当廉价的磷自由基引发剂以及硝酸盐供体。多种β-硝基氧膦酸酯以单罐方式高产交付。
更新日期:2018-10-11
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