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Visible-light-driven trimetallic Pt-Ag-Ni alloy nanoparticles for efficient nanoelectrocatalytic oxidation of alcohols
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.7 ) Pub Date : 2018-09-20 , DOI: 10.1016/j.jtice.2018.09.007
Pingping Song , Hui Xu , Jin Wang , Yangping Zhang , Fei Gao , Fangfang Ren , Yukihide Shiraishi , Caiqin Wang , Yukou Du

High-efficiency adsorption of solar energy is a lofty goal and the pursuit of efficient photocatalyst is also one of the tough challenges. It's a growing interesting in the technology that is on the basis of surface plasma resonance (SPR) plasma resonance of the alloy nanoparticles (NPs). We herein successfully design a facile class of trimetallic Pt-Ag-Ni alloy NPs that combined the advantages of electronic effect, size and synergistic effect. Impressively, the Pt2Ag1Ni1 NPs possess excellent electrocatalytic under visible light ethylene glycol oxidation reaction (EGOR) and glycerol oxidation reaction (GOR) with the mass activity founded to be: 7.99 and 4.88 A/mg, respectively. More significantly, SPR effect induces the optimal Pt-Ag-Ni NPs mass activity enhancement at 1.83 and 1.78 times higher under visible light than under environmental conditions. The design and SPR investigation of the trimetallic Pt-Ag-Ni alloy NPs in the research may provide a new approach for further development of high-performance nanocatalysts.



中文翻译:

可见光驱动的三金属Pt-Ag-Ni合金纳米粒子,用于醇的高效纳米电催化氧化

高效吸收太阳能是一个崇高的目标,追求高效的光催化剂也是艰巨的挑战之一。在基于合金纳米粒子(NPs)的表面等离子体共振(SPR)等离子体共振的技术中,它变得越来越有趣。我们在本文中成功设计了一种易用的三金属Pt-Ag-Ni合金NP,结合了电子效应,尺寸和协同效应的优点。令人印象深刻的是Pt 2 Ag 1 Ni 1NP在可见光下具有出色的电催化乙二醇氧化反应(EGOR)和甘油氧化反应(GOR),质量活性分别为7.99和4.88 A / mg。更重要的是,SPR效应在可见光下诱导的Pt-Ag-Ni NPs最佳质量活性增强是在环境条件下的1.83倍和1.78倍。三金属Pt-Ag-Ni合金纳米颗粒的设计和SPR研究为进一步开发高性能纳米催化剂提供了新的途径。

更新日期:2018-09-20
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