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Hydrogen purification with CO2-selective facilitated transport membranes
Current Opinion in Chemical Engineering ( IF 6.6 ) Pub Date : 2018-09-18 , DOI: 10.1016/j.coche.2018.09.004
Witopo Salim , W.S. Winston Ho

H2 is an important industrial gas, and high purity H2 is required for applications. Recent advances in both H2-selective and CO2-selective membranes for H2 purification are reviewed with an emphasis on the development of CO2-selective facilitated transport membranes for H2 purification. With CO2-selective facilitated transport membranes, examples of high-pressure and low-pressure H2 purification applications are discussed. In high-pressure H2 purification in the Integrated Gasification Combined Cycle (IGCC) operation, experimental and modeling results demonstrated the potential of amine-containing facilitated transport membranes to achieve an economically attractive cost of electricity. CO2-selective membranes for low-pressure H2 purification for fuel cells have been developed for both PEMFC and SOFC. The membranes have been scaled-up, and they have shown promising gas transport performances for the respective applications.



中文翻译:

用CO 2选择性促进转运膜纯化氢

H 2是重要的工业气体,应用中需要高纯度的H 2。在均为H的最新进展2 -选择性和CO 2用于h -选择性膜2纯化与对CO的发展强调审查2 -选择性促进输送膜用于h 2纯化。利用CO 2选择性促进输送膜,讨论了高压和低压H 2净化应用的示例。在高压H 2中在整体气化联合循环(IGCC)操作中进行纯化,实验和模型结果表明,含胺的便利运输膜具有实现经济上诱人的电费的潜力。已经针对PEMFC和SOFC开发了用于燃料电池的低压H 2净化的CO 2选择性膜。膜已按比例放大,并且在各自的应用中显示出令人鼓舞的气体传输性能。

更新日期:2018-09-18
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