当前位置: X-MOL 学术Chem. Commun. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
A tetrameric perylene diimide non-fullerene acceptor via unprecedented direct (hetero)arylation cross-coupling reactions†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-09-19 00:00:00 , DOI: 10.1039/c8cc06446f
Abby-Jo Payne 1, 2, 3 , Jiali Song 4, 5, 6 , Yanming Sun 4, 5, 6 , Gregory C. Welch 1, 2, 3
Affiliation  

This study reports on the synthesis of an indancenodithiophene perylene diimide tetramer via unique direct (hetero)arylation reactivity. The thiophene based core structure is shown to be easily functionalized with four perylene diimides at the four active C–H positions. This new reactivity provides a simple synthetic pathway towards tetrameric perylene diimides which have emerged as one of the best classes of electron acceptors for organic solar cells.

中文翻译:

四聚体per二酰亚胺非富勒烯受体通过前所未有的直接(杂)芳基化交叉偶联反应

这项研究报告了通过独特的直接(杂)芳基化反应合成茚并二噻吩per二酰亚胺四聚体的方法。基于噻吩的核心结构显示很容易在四个活泼的C–H位置被四个per二酰亚胺官能化。这种新的反应性为四聚per二酰亚胺提供了一条简单的合成途径,而四聚per二酰亚胺已成为有机太阳能电池的最佳电子受体类别之一。
更新日期:2018-09-19
down
wechat
bug