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A degradable fluorinated surfactant for emulsion polymerization of vinylidene fluoride†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-09-18 00:00:00 , DOI: 10.1039/c8cc05290e
Sanjib Banerjee 1, 2, 3, 4, 5 , Judith Schmidt 6, 7, 8, 9 , Yeshayahu Talmon 6, 7, 8, 9 , Hisao Hori 1, 10, 11, 12, 13 , Takuma Asai 1, 10, 11, 12, 13 , Bruno Ameduri 5, 14, 15, 16, 17
Affiliation  

An original degradable fluorinated surfactant, 3-hydroxy-2-(trifluoromethyl)propanoic acid (MAF-OH), was applied for the emulsion polymerization of vinylidene fluoride (VDF) to yield a latex of PVDF, consisting of typically 100 nm particle diameters. This surfactant was shown to be easily decomposed in subcritical water, releasing fluoride anions. The % reversed head-to head (H–H) addition is greatly minimized (2.4%) in the PVDF, prepared in the presence of MAF-OH surfactant.

中文翻译:

用于偏二氟乙烯乳液聚合的可降解氟化表面活性剂

将原始的可降解氟化表面活性剂3-羟基-2-(三氟甲基)丙酸(MAF-OH)应用于偏二氟乙烯(VDF)的乳液聚合,以生产PVDF胶乳,该胶乳的粒径通常为100 nm。该表面活性剂显示在亚临界水中易分解,释放出氟离子。在MAF-OH表面活性剂存在下制备的PVDF中,头对头(H–H)反向添加的百分比大大降低(2.4%)。
更新日期:2018-09-18
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