Expedient stereospecific Co-catalyzed tandem C–N and C–O bond formation of N-methylanilines with styrene oxides†,Chemical Communications

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Expedient stereospecific Co-catalyzed tandem C–N and C–O bond formation of N-methylanilines with styrene oxides†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-09-18 00:00:00 , DOI: 10.1039/c8cc06223d
Vanaparthi Satheesh _{1,

2,

3,

4} , Sundaravel Vivek Kumar _{1,

2,

3,

4} , Tharmalingam Punniyamurthy _{1,

2,

3,

4}

Affiliation

Cobalt(II)-catalyzed stereospecific coupling of N-methylanilines with styrene oxides is developed via tandem C–N and C–O bond formation using tert-butyl hydroperoxide (TBHP) as an oxidant. Optically active epoxide can be reacted with high optical purity.

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