当前位置: X-MOL 学术ACS Omega › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Molecular Structure of the Photo-Oxidation Product of Ellagic Acid in Solution
ACS Omega ( IF 4.1 ) Pub Date : 2018-09-14 00:00:00 , DOI: 10.1021/acsomega.8b01716
Hisashi Tokutomi 1 , Takashi Takeda 1, 2 , Norihisa Hoshino 1, 2 , Tomoyuki Akutagawa 1, 2
Affiliation  

The photoreaction of the antioxidant ellagic acid (EA) elicits a drastic coloration in solution from colorless to yellow in aerated tetrahydrofuran, which appears as a new absorption band at 405 nm. Analysis of the X-ray crystal structure suggests that the photo-oxidation product of EA is a multiple cleavage π-structure (Ox-EA) that results from the interaction of EA with singlet oxygen followed by sequential cleavage and rearrangement steps.

中文翻译:

溶液中鞣花酸光氧化产物的分子结构

抗氧化剂鞣花酸(EA)的光反应在充气的四氢呋喃中引起溶液从无色到黄色的剧烈着色,在405 nm处显示为新的吸收带。对X射线晶体结构的分析表明,EA的光氧化产物是多重裂解的π结构(Ox-EA),其由EA与单线态氧的相互作用,随后的顺序裂解和重排步骤产生。
更新日期:2018-09-14
down
wechat
bug