Hydrogen peroxide production via a redox reaction of N,N′-dimethyl-2,6-diaza-9,10-anthraquinonediium by addition of bisulfite†,Chemical Communications

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Hydrogen peroxide production via a redox reaction of N,N′-dimethyl-2,6-diaza-9,10-anthraquinonediium by addition of bisulfite†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-09-13 00:00:00 , DOI: 10.1039/c8cc05548c
Igor V. Kolesnichenko _{1,

2,

3,

4,

5} , P. Rogelio Escamilla _{1,

2,

3,

4,

5} , Jason A. Michael _{1,

2,

3,

4,

5} , Vincent M. Lynch _{1,

2,

3,

4,

5} , David A. Vanden Bout _{1,

2,

3,

4,

5} , Eric V. Anslyn _{1,

2,

3,

4,

5}

Affiliation

We demonstrate that bisulfite can be used for reduction of a highly electrophilic anthraquinone derivative, N,N′-dimethyl-2,6-diaza-9,10-anthraquinonediium (DAAQ), and subsequent autoxidation generates an equivalent of hydrogen peroxide. The mechanism for DAAQ reduction by bisulfite, DAAQ electrochemistry, and use of a simple test strip assay for H₂O₂, are described.

中文翻译：

过氧化氢的生产通过的氧化还原反应Ñ，Ñ '通过加入二甲基-2,6-二氮杂-9,10-亚硫酸氢anthraquinonediium †

我们证明了亚硫酸氢盐可用于还原高度亲电的蒽醌衍生物，N，N'-二甲基-2,6-二氮杂-9,10-蒽醌二鎓（DAAQ），随后的自氧化反应产生的过氧化氢当量。描述了通过亚硫酸氢盐还原DAAQ的机理，DAAQ电化学以及H ₂ O ₂的简单测试条测定法的使用。

更新日期：2018-09-13

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