Reaction of the first homoleptic U(III) guanidinate complex with diphenyldiazomethane results in two-electron oxidation of U(III) to U(V) and isolation of a U(V) hydrazido complex. Corresponding U(V) imido, U(V) oxo, and U(IV) azido complexes were also synthesized for structural comparison.

中文翻译：

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二苯基重氮甲烷对均化的U（iii）胍盐络合物的双电子氧化†

第一均质U（III）胍盐配合物与二苯基重氮甲烷的反应导致U（III）到U（V）的两电子氧化，并分离出U（V）肼基配合物。还合成了相应的U（V）亚氨基，U（V）氧代和U（IV）叠氮基络合物，用于结构比较。