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Sequential Production of Xylose, Levulinic Acid and Activated Carbon from Pine Wood
ChemistrySelect ( IF 2.1 ) Pub Date : 2018-09-11 , DOI: 10.1002/slct.201802075
Shimin Kang 1, 2 , Wenkang Lai 1, 2 , Xiaodong Yin 1, 2 , Zhezhe Peng 1, 2 , Junling Tu 1, 2 , Si-Min Huang 1, 2
Affiliation  

In this work, a sequential production of bioenergy platform intermediates (i. e., xylose and levulinic acid (LA)) and carbon materials from pine wood was developed by a three‐step conversion technology. Firstly, the hemicellulose in pine wood was hydrolyzed, obtaining 12.8 wt% xylose and 68.9 wt% solid products containing cellulose and lignin. Secondly, the solid products were hydrolyzed, obtaining 30.6 wt% LA and 42.0 wt% solid residues containing humins and lignin. Thirdly, the solid residues were used for activated carbon (AC) production through potassium hydrate (KOH) activation followed by pyrolysis from 400–800 oC. An AC obtained at a pyrolysis temperature of 800 oC had a high Brunauer‐Emmett‐Teller (BET) surface area of 2436 m2/g and pore volume of 0.91 cm3/g, which exhibited an excellent reactive brilliant red X‐3B (RBRX‐3B) adsorption capacity of 892 mg/g. As a case, 1000 g of pine wood finally produced 128 g xylose, 211 g LA and 39 g high‐performance activated carbon.

中文翻译:

从松木中依次生产木糖,戊酸和活性炭

在这项工作中,通过三步转化技术开发了从松木中顺序生产生物能源平台中间体(即木糖和乙酰丙酸(LA))和碳材料的方法。首先,将松木中的半纤维素水解,得到12.8重量%的木糖和68.9重量%的含有纤维素和木质素的固体产物。其次,将固体产物水解,得到30.6重量%的LA和42.0重量%的含有腐殖质和木质素的固体残余物。第三,固体残留物用于通过水合钾(KOH)活化,然后在400–800 o C进行热解生产活性炭(AC)。在800 o C的热解温度下获得的AC具有较高的Brunauer-Emmett-Teller (BET)表面积2436 m 2/ g,孔体积为0.91 cm 3 / g,它具有892 mg / g的出色的活性艳红X-3B(RBRX-3B)吸附能力。最终,以1000克松木为例,产生了128克木糖,211克LA和39克高性能活性炭。
更新日期:2018-09-11
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