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Spin-Hamiltonian parameters and zero-field splitting of impurity Gd3+ ions in SrY2O4 crystal
Journal of Magnetism and Magnetic Materials ( IF 2.7 ) Pub Date : 2019-01-01 , DOI: 10.1016/j.jmmm.2018.09.044
B.F. Gabbasov , D.G. Zverev , I.F. Gilmutdinov , R.G. Batulin , A.G. Kiiamov , S.I. Nikitin , R.V. Yusupov

Abstract Electron paramagnetic resonance (EPR) study of the impurity Gd3+ ions in the multi-site SrY2O4 crystal isostructural to the magnetically-frustrated SrGd2O4 compound is reported. Analysis of the angular dependences of the EPR spectra at room temperature allowed us to establish the spin-level energy patterns in the ground states of the Gd3+ ions at the Y(1) and Y(2) sites. Parameters of the spin-Hamiltonian in the frames related to the crystal axes and to the principal center axes are determined.

中文翻译:

SrY2O4晶体中杂质Gd3+离子的自旋哈密顿参数和零场分裂

摘要 报道了与磁受阻 SrGd​​2O4 化合物同构的多位点 SrY2O4 晶体中杂质 Gd3+ 离子的电子顺磁共振 (EPR) 研究。室温下 EPR 光谱的角度依赖性分析使我们能够在 Y(1) 和 Y(2) 站点的 Gd3+ 离子的基态中建立自旋能级能量模式。确定与晶轴和主中心轴相关的坐标系中的自旋哈密顿参数。
更新日期:2019-01-01
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