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Robust heterometallic MOF catalysts for the cyanosilylation of aldehydes†
Inorganic Chemistry Frontiers ( IF 7 ) Pub Date : 2018-09-06 00:00:00 , DOI: 10.1039/c8qi00811f
Jia-Jia Du 1, 2, 3, 4 , Xiang Zhang 4, 5, 6, 7 , Xiao-Ping Zhou 4, 5, 6, 7 , Dan Li 4, 5, 6, 7
Affiliation  

In this work, Zn2+ and Cu2+ ions are doped into a Mn2+ based frail MOF (STU-2) to form heterometallic MOFs. These metal doped MOFs show a good stability and heterogeneous catalytic activity for the cyanosilylation reactions of aromatic aldehydes. The catalysts can be reused at least for three cycles.

中文翻译:

用于醛氰基硅烷化的耐用的杂金属MOF催化剂

在这项工作中,将Zn 2+和Cu 2+离子掺杂到Mn 2+基脆弱MOF(STU-2)中以形成异金属MOF。这些金属掺杂的MOF对芳族醛的氰基硅烷化反应显示出良好的稳定性和非均相的催化活性。催化剂可以重复使用至少三个循环。
更新日期:2018-09-06
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