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Co2[email protected]2O4 bi-functional electrocatalyst with low overpotential for water splitting in wide range pH electrolytes
Journal of Colloid and Interface Science ( IF 9.9 ) Pub Date : 2018-09-06 , DOI: 10.1016/j.jcis.2018.09.017
Ying Liu , Fei Yang , Wei Qin , Guowei Yang

The Co2[email protected]2O4 bi-functional electrocatalyst was fabricated for hydrogen evolution reaction and oxygen evolution reaction in acidic, neutral and alkaline media. The Co2[email protected]2O4 in alkaline media exhibites an extremely low overpotential of 170 mV in oxygen evolution to achieve a current density of 10 mA cm−2 and produces stable water splitting nearly 30 h. The anchored-Co2P can enhance the electrochemical performance of pristine NiCo2O4 as well as increase the tolerance in acidic media of NiCo2O4. Additional, the Co2P is oxidized to oxides/hydroxides species during the electrocatalytic reaction, which acts as the active centers of the electrocatalysis. The Co2[email protected]2O4 catalyst can be used as an effective bifunctional synergistic center in a wide range of pH values (from 0 to 14).



中文翻译:

具有低超电势的Co 2 [受电子邮件保护] 2 O 4双功能电催化剂,可在宽范围的pH电解液中进行水分解

制备了Co 2 [受电子邮件保护的] 2 O 4双功能电催化剂,用于在酸性,中性和碱性介质中的氢气释放反应和氧气释放反应。碱性介质中的Co 2 [受电子邮件保护] 2 O 4在氧气释放中表现出极低的170 mV过电势,可实现10 mA cm -2的电流密度,并在近30 h内产生稳定的水分解。锚定的钴2 P能够提高原始镍钴的电化学性能2 ö 4以及增加的公差在镍钴的酸性介质2 ö 4。另外,在电催化反应期间,Co 2 P被氧化成氧化物/氢氧化物,其充当电催化的活性中心。Co 2 [受电子邮件保护的] 2 O 4催化剂可以在很宽的pH值范围(0至14)中用作有效的双功能协同中心。

更新日期:2018-09-06
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