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Na2CO3-Catalyzed O-Acylation of Phenols for the Synthesis of Aryl Carboxylates with Use of Alkenyl Carboxylates
Synlett ( IF 2 ) Pub Date : 2018-08-31 , DOI: 10.1055/s-0037-1610265
Xiao-Yu Zhou 1 , Xia Chen 1
Affiliation  

Inorganic base-catalyzed O-acylation of phenol and its derivatives has been developed. The procedure provides an efficient catalysis system for the preparation of aryl carboxylates with alkenyl carboxylates as acyl reagents. The reaction proceeded smoothly by using ­Na2CO3 as the catalyst in MeCN to produce the corresponding aryl carboxylates in good to excellent yields.

中文翻译:

Na2CO3 催化的苯酚 O-酰化反应用于使用烯基羧酸盐合成芳基羧酸盐

已开发出无机碱催化苯酚及其衍生物的 O-酰化。该方法为以烯基羧酸盐作为酰基试剂制备芳基羧酸盐提供了有效的催化体系。在 MeCN 中使用 Na2CO3 作为催化剂, 反应顺利进行, 以良好到极好的收率生产相应的芳基羧酸酯。
更新日期:2018-08-31
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