A halogen bond-donor amino acid for organocatalysis in water†,Chemical Communications

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A halogen bond-donor amino acid for organocatalysis in water†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-08-30 00:00:00 , DOI: 10.1039/c8cc06010j
Greta Bergamaschi _{1,

2,

3,

4} , Luisa Lascialfari _{1,

2,

3,

4} , Andrea Pizzi _{1,

2,

3,

4} , Maria Isabel Martinez Espinoza _{1,

2,

3,

4} , Nicola Demitri _{4,

5,

6,

7} , Alberto Milani _{1,

2,

3,

4} , Alessandro Gori _{4,

8,

9} , Pierangelo Metrangolo _{1,

2,

3,

4}

Affiliation

Herein we report a halogen bond-donor amino acid, 4-iodotetrafluorophenylalanine, which behaves as a catalyst for the aqueous synthesis of bis-(heterocyclic)methanes. We also provide experimental evidence that halogen bonding is a plausible explanation for the observed catalytic effect.

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