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Process conditions for the manufacture of highly micro-mesoporous eco-friendly activated carbon from artocarpus integer bio-waste by steam activation
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.7 ) Pub Date : 2018-08-31 , DOI: 10.1016/j.jtice.2018.08.011
Geetha Selvaraju , Nor Kartini Abu Bakar

In this paper, for the first time, we report the process conditions to obtain highly micro-mesoporous eco-friendly activated carbon (Eco-AC) from Artocarpus integer bio-waste by steam activation. The proposed novel material provides a green alternative to existing chemically activated bio-wastes for the preparation of highly micro-mesoporous activated carbon. The influences of pyrolysis temperature and duration followed by steam-gasification temperature and duration on the pore structure and yield of Eco-ACs were explored in this study. The prepared Eco-ACs had been characterized by N2 adsorption-desorption analysis and FESEM. Based on our experimental results, the optimum technology conditions for preparing highly micro-mesoporous Eco-AC are: pyrolysis temperature, 700°C; pyrolysis duration, 60 min; steam-gasification temperature, 750°C; and steam-gasification duration, 60 min. The optimal Eco-AC has a BET surface area of 852.63 m2/g, Langmuir surface area of 964.79 m2/g, t-plot micropore surface area of 506.03 m2/g, t-plot mesopore surface area of 346.60 m2/g, total pore volume of 0.632 cm3/g, BET average pore diameter of 2.967 nm and BJH average pore diameter of 5.489 nm with a reasonable yield, 33.5%, making it a promising economical and eco-friendly carbon material for use in environmental separation technologies and water treatment.



中文翻译:

通过蒸汽活化从面包果整数生物废料生产高微孔环保型活性炭的工艺条件

在本文中,我们首次报告了通过蒸汽活化从面包果整数生物废料中获得高度微中观生态友好型活性炭(Eco-AC)的工艺条件。提出的新型材料为现有的化学活化生物废料提供了绿色替代品,用于制备高微介孔活性炭。本研究探讨了热解温度和持续时间,继之以汽化温度和持续时间对Eco-AC的孔结构和产率的影响。通过N 2吸附-解吸分析和FESEM对制备的Eco-AC进行了表征。根据我们的实验结果,制备高微介孔Eco-AC的最佳工艺条件为:热解温度为700°C;热解持续时间为60分钟;汽化温度750°C;蒸汽气化持续时间为60分钟。最佳的Eco-AC的BET表面积为852.63 m 2 / g,Langmuir表面积为964.79 m 2 / g,t图解微孔表面积为506.03 m 2 / g,t图解中孔表面积为346.60 m 2 / g,总孔体积为0.632 cm 3 / g,BET平均孔径为2.967 nm,BJH平均孔径为5.489 nm,产率合理,为33.5%,使其成为一种有前景的经济,环保的碳材料,可用于环境分离技术和水处理。

更新日期:2018-08-31
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