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Clathrochelate Metalloligands in Supramolecular Chemistry and Materials Science
Accounts of Chemical Research ( IF 18.3 ) Pub Date : 2018-08-29 00:00:00 , DOI: 10.1021/acs.accounts.8b00306
Suzanne M. Jansze 1 , Kay Severin 1
Affiliation  

The term “clathrochelate” describes a complex in which a coordinatively saturated metal ion is surrounded by a macropolycyclic ligand. First examples of clathrochelate complexes were reported 50 years ago. Meanwhile, the synthesis and reactivity of clathrochelates have been investigated in detail, and numerous applications have been explored. In this Account, we summarize work on the utilization of transition metal clathrochelates as metalloligands in supramolecular chemistry and materials science, with special focus on results from our group.

中文翻译:

超分子化学和材料科学中的笼形螯合物金属配体

术语“笼形螯合物”描述了其中配位饱和金属离子被大环多环配体包围的络合物。笼形螯合物的第一个例子是50年前报道的。同时,对笼形螯合物的合成和反应性进行了详细研究,并探索了许多应用。在此报告中,我们总结了在超分子化学和材料科学中利用过渡金属笼形螯合物作为金属配体的工作,特别关注了我们小组的结果。
更新日期:2018-08-29
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