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Structural reorganization in a hydrogen-bonded organic framework†
New Journal of Chemistry ( IF 3.3 ) Pub Date : 2018-08-29 00:00:00 , DOI: 10.1039/c8nj02738b
Javier Castells-Gil 1, 2, 3, 4 , Natalia M. Padial 1, 2, 3, 4 , Carlos Martí-Gastaldo 1, 2, 3, 4
Affiliation  

Self-recognition of 3,3′,5,5′-azobenzenetetracarboxylic acid drives the formation of a grid-like anionic hydrogen-bonded framework with channels occupied by organic cations. This supramolecular solid is capable of reorganizing its connectivity in the presence of specific guests into a different crystalline architecture by sequential dissolution and recrystallization.

中文翻译:

氢键有机骨架中的结构重组

3,3',5,5'-偶氮苯四甲酸的自识别驱动了网格状阴离子氢键键合骨架的形成,该通道具有被有机阳离子占据的通道。这种超分子固体能够通过顺序溶解和重结晶在特定客体存在下将其连通性重组为不同的晶体结构。
更新日期:2018-08-29
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