当前位置: X-MOL 学术Synlett › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
New Cyano-Group-Containing 1,3-Oxaselenoles: Nucleophilic Substitution of a Cyano Group with Rearrangement
Synlett ( IF 2 ) Pub Date : 2018-08-24 , DOI: 10.1055/s-0037-1609939
Andrey Kachanov 1 , Andrey Zamaraev 2 , Andrey Gerasimenko 3 , Konstantin Maslov 1 , Oleg Slabko 1 , Vladimir Kaminskii 1
Affiliation  

New cyano-group-containing 1,3-oxaselenoles were obtained by the treatment of aroylacetonitriles with selenium(IV) oxide. The resulting products were shown to react with ammonia, hydrazine, or primary amines; this reaction was accompanied by aryl rearrangement.

中文翻译:

新的含氰基的 1,3-氧杂硒代醇:氰基重排的亲核取代

通过用氧化硒 (IV) 处理芳酰基乙腈,获得了新的含氰基 1,3-氧杂硒代烯醇。所得产物显示与氨、肼或伯胺反应;该反应伴随着芳基重排。
更新日期:2018-08-24
down
wechat
bug