Synthesis of (±)‐Merrilactone A by a Desymmetrization Strategy,Chemistry - A European Journal

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Synthesis of (±)‐Merrilactone A by a Desymmetrization Strategy
Chemistry - A European Journal ( IF 4.3 ) Pub Date : 2018-10-18 , DOI: 10.1002/chem.201804195
Wentan Liu _{1,

2} , Bo Wang _{1,

3}

Affiliation

A concise synthesis of (±)‐merrilactone A has been accomplished featuring desymmetrization of a C_s‐symmetric dilactone, Rh^I‐catalyzed intramolecular hydroacylation of a 4‐alkynal, and Ti^III‐mediated reductive radical cyclization of epoxy‐allene.

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