A electrochemical method for the synthesis of 3,5‐disubstituted‐1,2,4‐thiadiazoles through NH₄I‐mediated dimerization of thioamides is reported. Using the inexpensive NH₄I as electrolyte and catalyst, this electrosynthesis approach requires no oxidizing agents and enables the convenient production of diverse 1,2,4‐thiadiazoles products. The approach is an example of S−N bond construction through the electrochemical method.

中文翻译：

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通过NH4I介导的硫酰胺二聚体电化学合成3,5-二取代-1,2,4-噻二唑

报道了一种通过NH ₄ I介导的硫酰胺二聚反应合成3,5-二取代-1,2,4-噻二唑的电化学方法。使用廉价的NH ₄ I作为电解质和催化剂，这种电合成方法不需要氧化剂，并且可以方便地生产各种1,2,4-噻二唑产品。该方法是通过电化学方法构建S–N键的一个示例。