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Enhanced photocatalytic activity of TiO2 by micrometer-scale flower-like morphology for gaseous elemental mercury removal
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-08-14 , DOI: 10.1016/j.catcom.2018.08.012
Yang Ling , Chong Zhang , Jiang Wu , Weixing Xu , Yongfeng Qi , Ping He , Lili Zhao , Yu Guan , Zhen Zhang , Yuzhuo Tian

A flower-like TiO2 photocatlyst has been fabricated using hydrothermal method with the changing of sodium hydroxide volume to control the morphology so as to enhance the photocataltic activity. The as-prepared photocatalysts has entire anatase phase with numerous nanowires covered on its surface, which structure is conducive to the higher BET surface area (86.7910 m2/g) and lower recombination between holes and photoelectrons. The photocatalytic ability was tested by oxidation of gaseous Hg0 in a lab-scale reactor, and TiO2-5 is found to be the best efficiency and 80 °C is the optimum photocatalytic reaction temperature. The photocatalytic oxidation mechanism has also been proposed.



中文翻译:

微米级花状形态增强TiO 2的光催化活性,用于去除气态元素汞

利用水热法制备了花状的TiO 2光催化剂,改变氢氧化钠的体积来控制其形貌,从而增强光催化活性。所制备的光催化剂具有完整的锐钛矿相,其表面覆盖有许多纳米线,该结构有利于较高的BET表面积(86.7910 m 2 / g)和较低的空穴与光电子之间的重组。通过在实验室规模的反应器中氧化气态Hg 0来测试光催化能力,发现TiO 2 -5是最佳效率,而80°C是最佳光催化反应温度。还提出了光催化氧化机理。

更新日期:2018-08-14
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