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Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation†
Chemical Science ( IF 8.4 ) Pub Date : 2018-08-13 00:00:00 , DOI: 10.1039/c8sc02281j
Kai Yang 1 , Guan Zhang 1 , Qiuling Song 1, 2
Affiliation  

To develop a simple and efficient synthetic method for four-coordinate triarylboranes, we herein describe a tandem highly selective B–Cl/C–B cross-metathesis of two of the same or different arylboranes and C–H bond borylation to synthesize four-coordinate triarylboranes with a broad substrate scope. By switching substituent groups of the target molecules, different emission wavelengths can be achieved from 467 nm to 583 nm with aggregation-induced emission (AIE) properties.

中文翻译:

通过级联 B–Cl/C–B 交叉复分解和 C–H 键硼化作用合成四配位三芳基硼烷†

为了开发一种简单有效的四配位三芳基硼烷的合成方法,我们在此描述了两种相同或不同芳基硼烷的串联高选择性B-Cl/C-B交叉复分解和C-H键硼基化来合成四配位三芳基硼烷。三芳基硼烷具有广泛的底物范围。通过切换目标分子的取代基,可以实现从 467 nm 到 583 nm 的不同发射波长,并具有聚集诱导发射 (AIE) 特性。
更新日期:2018-08-13
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