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Self-supported gold/chitosan nanocatalyst for chemoselective hydrogenation in π-conjugated CCCO system
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-08-04 , DOI: 10.1016/j.catcom.2018.08.003
Anike H. Virgili , Leandro Luza , Jesum A. Fernandes , Tania M.H. Costa , Eliana W. de Menezes , Edilson V. Benvenutti

A self-supported gold/chitosan nanocatalyst was easily obtained by drying a water dispersion followed by powdering it. In this system chitosan acts concomitantly as a stabilizer and support for gold nanoparticles. The self-supported gold/chitosan was applied as catalyst for CC and CO hydrogenation in conjugate and non-conjugate systems. The catalyst showed activity, driving selectivity to saturated alcohols or saturated ketones (selectivities ≥99%) depending on the reducing agent used, NaBH4 or H2 respectively. When H2 was used, the catalyst showed activity only in conjugate CCCO, forming saturated aldehydes and ketones. For isolated CC, CO or conjugate CCCC bonds, no activity was observed.



中文翻译:

自担金/壳聚糖纳米催化剂在π共轭C C C O体系中的化学选择性加氢

通过干燥水分散体然后将其粉化,容易获得自支撑的金/壳聚糖纳米催化剂。在该系统中,壳聚糖同时充当金纳米颗粒的稳定剂和载体。自负载金/壳聚糖被用作共轭和非共轭体系中C C和C O加氢的催化剂。催化剂表现出活性,根据所用还原剂分别为NaBH 4或H 2,对饱和醇或饱和酮(选择性≥99%)产生选择性。当使用H 2时,该催化剂仅在共轭C C C O中显示活性,形成饱和的醛和酮。对于分离的C C,C O或共轭C CC C键,未观察到活性。

更新日期:2018-08-04
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