Polyfluorinated indans and tetralins are carbonylated under the action of CO/SbF₅ at room temperature and atmospheric pressure. Perfluoroindan and its 4-CF₃, 5-CF₃, 5-CH₃, 1,1-H,H derivatives add two CO molecules to form the corresponding dimethyl indan-1,1-dicarboxylates after methanolysis, and/or 1-hydroindan-1-carboxylic acids after hydrolysis. 1-X-Perfluoroindans (XCF₃, C₂F₅, C₆F₅, H) and 1-X-perfluorotetralins (XC₂F₅, C₆F₅) add one CO molecule at the 1-position to give the corresponding 1-carbonyl fluorides. Reaction of the latter with methanol gives methyl esters, whereas hydrolysis is accompanied by decarboxylation. Perfluoro-2,3-dihydrobenzofuran under the action of CO/SbF₅ gives both mono- and dicarbonylation products.

在室温和大气压下，在CO / SbF ₅的作用下，将多氟茚满和四氢化萘羰基化。Perfluoroindan及其4-CF ₃，5-CF ₃，5-CH ₃，1,1- H，H的衍生物添加两个CO分子以形成相应的甲醇分解后二甲基茚满-1,1-二羧酸，和/或1-水解后的氢化茚满-1-羧酸。1-X-全氟茚满（X CF ₃，C ₂ F ₅，C ₆ F ₅，H）和1-X-全氟四氢化萘（X C ₂ F ₅，C ₆ F _5））在1位加一个CO分子，得到相应的1-羰基氟化物。后者与甲醇反应得到甲酯，而水解伴随脱羧作用。全氟-2,3-二氢苯并呋喃在CO / SbF ₅的作用下同时生成单羰基和二羰基化产物。