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High-performance Förster resonance energy transfer-based dye-sensitized photocatalytic H2 evolution with graphene quantum dots as the homogeneous energy donor†
Photochemical & Photobiological Sciences ( IF 3.1 ) Pub Date : 2018-07-30 00:00:00 , DOI: 10.1039/c8pp00227d
Yonggang Lei 1, 2, 3, 4, 5 , Yuan Xue 1, 2, 3, 4, 5 , Yanan Li 1, 2, 3, 4, 5 , Xiangyu Liu 1, 2, 3, 4, 5 , Fang Wang 1, 2, 3, 4, 5 , Shixiong Min 1, 2, 3, 4, 5
Affiliation  

A high-performance dye-sensitized photocatalytic H2 evolution system was developed based on Förster resonance energy transfer (FRET) by employing water-soluble and highly photoluminescent N,S codoped graphene quantum dots (NSGQDs) as the homogeneous energy donor, erythrosin B (ErB) as the sensentizing dye, and platinum nanoparticles (Pt NPs) as the catalyst. NSGQDs absorbed high-energy photons that undergo FRET to transfer the excitation energy to the sensitizing ErB for maximizing light absorption and also served as an electron transfer and loading matrix of Pt NPs for accelarating the electron transfer; as a result, the ErB-sensitized NSGQD-Pt system afforded much higher H2 evolution activity than the NSGQD-free dye-sensitized system.

中文翻译:

以石墨烯量子点为均质供体 的高性能基于Förster共振能量转移的染料敏化光催化H 2演化

基于水溶性和高度光致发光的N,S共掺杂石墨烯量子点(NSGQDs)作为均相能量供体,赤藓红B(Ferster共振能量转移(FRET)),开发了一种高性能的染料敏化光催化H 2析出体系。 ErB)作为敏化染料,铂纳米颗粒(Pt NPs)作为催化剂。NSGQDs吸收经过FRET的高能光子,以将激发能量转移到敏化ErB上,以使光吸收最大化,并且还充当Pt NPs的电子转移和负载矩阵,以加速电子转移;结果,ErB致敏的NSGQD-Pt系统比不含NSGQD的染料致敏系统具有更高的H 2释放活性。
更新日期:2018-07-30
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