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Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-07-26 00:00:00 , DOI: 10.1039/c8cc04736g
Ariane Brandenburg 1 , Denis S Krylov , Alexander Beger , Anja U B Wolter , Bernd Büchner , Alexey A Popov
Affiliation  

Carbide clusterfullerene DyYTiC@C80-Ih with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The SMM properties of DyYTiC@C80 are compared to those of DySc2N@C80 and the influence of the central atom in the endohedral cluster is analyzed.

中文翻译:

碳化物团簇富勒烯 DyYTiC@C80 具有内嵌团簇中的三种不同金属及其单离子磁性†

以甲烷为反应气体,通过电弧放电合成得到了内嵌簇中含有三种不同金属原子的碳化物簇富勒烯DyYTiC@C 80 - I h ,并通过HPLC成功分离。该化合物表现出单分子磁性(SMM),磁滞低于8 K。将DyYTiC@C 80与DySc 2 N@C 80的SMM性质进行比较,并分析了内嵌簇中心原子的影响。
更新日期:2018-07-26
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