The development of ionic‐liquid‐derived functional materials would be vital for stimulation of the interdisciplinary research in the fields of ionic liquid chemistry and material science. Here, a series of novel poly(ionic liquid)s with explosive capability were designed and prepared by introducing the energetic nitrato group and nitro‐rich anions, such as nitrate, dinitramide, and nitroform into the polymeric chains. The as‐synthesized explosive poly(ionic liquid)s (E‐PILs) were fully characterized, and their physicochemical and detonation properties were investigated. All E‐PILs show higher detonation performances than state‐of‐the‐art energetic polymers including glycidyl azide polymer (GAP) and poly(glycidyl nitrate) [poly(GLYN)]. Some E‐PILs exhibit higher calculated detonation velocities and pressures than 2,4,6‐trinitrotoluene (TNT). These E‐PILs are promising candidates for applications as new high‐performance energetic polymers.

中文翻译：

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设计作为新型含能聚合物的爆炸性聚离子液体

离子液体衍生功能材料的开发对于促进离子液体化学和材料科学领域的跨学科研究至关重要。在这里，通过将高能的硝酸根基团和富含硝酸根的阴离子（例如硝酸根，二硝酰胺和硝基仿）引入聚合物链中，设计并制备了一系列具有爆炸性的新型聚离子液体。对合成的爆炸性聚离子液体（E-PIL）进行了充分表征，并对其理化和爆轰性能进行了研究。与最先进的高能聚合物（包括缩水甘油叠氮化物聚合物（GAP）和聚缩水甘油硝酸盐）[poly（GLYN））相比，所有E-PIL的爆震性能都更高。一些E-PIL的计算爆炸速度和压力要比2,4,6-三硝基甲苯（TNT）高。