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Half-cell and full-cell applications of sodium ion batteries based on carbon-coated Na3Fe0.5V1.5(PO4)3 nanoparticles cathode
Electrochimica Acta ( IF 6.6 ) Pub Date : 2018-07-17 , DOI: 10.1016/j.electacta.2018.07.087
Renming Zhan , Bolei Shen , Qiuju Xu , Youquan Zhang , Yushan Luo , Heng Liu , Hao Chen , Feng Liu , Changming Li , Maowen Xu

Pristine Na3Fe0.5V1.5(PO4)3 and carbon-coated Na3Fe0.5V1.5(PO4)3 nano-particles are synthesized by one-step solid-phase reaction method. The full battery based on Na3Fe0.5V1.5(PO4)3@C nano-particles as cathode and commercial hard carbon as anode outputs a high working voltage about 3.3 V and exhibits superior-rate performance. While the rate increases from 0.5 to 1, 2 and 5 C, the discharge capacity of full battery slightly decreases from 110 to 94, 88, 79 mA h g−1 gradually. Moreover, it shows excellent cycle stability with a capacity retention of 93.8% after 200 cycles at 0.5 C.



中文翻译:

基于碳包覆的Na 3 Fe 0.5 V 1.5(PO 43纳米粒子阴极的钠离子电池的半电池和全电池应用

通过一步固相反应法合成了原始的Na 3 Fe 0.5 V 1.5(PO 43和碳包覆的Na 3 Fe 0.5 V 1.5(PO 43纳米颗粒。基于Na 3 Fe 0.5 V 1.5(PO 43的完整电池@C纳米粒子作为阴极,商用硬质碳作为阳极,可输出约3.3 V的高工作电压,并具有较高的速率性能。当速率从0.5 C增加到1、2和5 C时,充满电的电池的放电容量从110 mA h g -1逐渐减小到94、88、79 mA h g -1。而且,它显示出出色的循环稳定性,在0.5 C下200次循环后的容量保持率为93.8%。

更新日期:2018-07-17
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