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Cobalt(ii)-catalyzed regioselective C–H halogenation of anilides†
Organic & Biomolecular Chemistry ( IF 3.2 ) Pub Date : 2018-07-10 00:00:00 , DOI: 10.1039/c8ob01448e Ze-lin Li 1, 2, 3, 4 , Kang-kang Sun 1, 2, 3, 4 , Chun Cai 1, 2, 3, 4
Organic & Biomolecular Chemistry ( IF 3.2 ) Pub Date : 2018-07-10 00:00:00 , DOI: 10.1039/c8ob01448e Ze-lin Li 1, 2, 3, 4 , Kang-kang Sun 1, 2, 3, 4 , Chun Cai 1, 2, 3, 4
Affiliation
A cobalt-catalyzed regioselective C–H halogenation methodology is reported herein. The highlight of this work is the highly selective C–H functionalization of anilides, which results in high-yielding, versatile, and practical halogenated products. Thereby, brominations, chlorinations and iodinations of many electron-rich and electron-deficient anilides were achieved in a highly selective fashion. Mechanistic studies with respect to the pathway of the reaction are also described.
中文翻译:
钴(ii)催化的苯甲酸酯的区域选择性C–H卤化†
本文报道了钴催化的区域选择性CH卤化方法。这项工作的重点是对苯甲酸酯的高选择性C–H官能化,这将产生高产率,多功能且实用的卤化产物。由此,以高度选择性的方式实现了许多富电子和电子贫乏的酸酐的溴化,氯化和碘化。还描述了有关反应途径的机理研究。
更新日期:2018-07-10
中文翻译:
钴(ii)催化的苯甲酸酯的区域选择性C–H卤化†
本文报道了钴催化的区域选择性CH卤化方法。这项工作的重点是对苯甲酸酯的高选择性C–H官能化,这将产生高产率,多功能且实用的卤化产物。由此,以高度选择性的方式实现了许多富电子和电子贫乏的酸酐的溴化,氯化和碘化。还描述了有关反应途径的机理研究。