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Fluoro- and Chloroferrocene: From 2- to 3-Substituted Derivatives
Organometallics ( IF 2.8 ) Pub Date : 2018-07-10 , DOI: 10.1021/acs.organomet.8b00384
Mehdi Tazi 1 , Madani Hedidi 1, 2 , William Erb 1 , Yury S. Halauko 3 , Oleg A. Ivashkevich 3 , Vadim E. Matulis 4 , Thierry Roisnel 1 , Vincent Dorcet 1 , Ghenia Bentabed-Ababsa 2 , Florence Mongin 1
Affiliation  

The ferrocene halogen “dance” has been deemed hardly controllable. Here, we describe the first efficient examples of this reaction. Conversion of 1-fluoro-2-iodo (or 1-chloro-2-iodo) to 1-fluoro-3-iodo (or 1-chloro-3-iodo) ferrocenes was ensured by suitably protecting the free 5-position.

中文翻译:

氟和氯二茂铁:从2到3取代的衍生物

二茂铁卤素的“舞蹈”被认为是难以控制的。在这里,我们描述了该反应的第一个有效实例。通过适当地保护游离的5-位确保了1-氟-2-碘(或1-氯-2-碘)到1-氟-3-碘(或1-氯-3-碘)二茂铁的转化。
更新日期:2018-07-12
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