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DDQ‐Promoted Allylic C−H Phosphorylation of 1,3‐Diarylpropenes
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2018-07-26 , DOI: 10.1002/adsc.201800804
Qian Chen 1, 2 , Chunxiao Wen 1 , Xiaofeng Wang 1 , Guodian Yu 1 , Yingcong Ou 1 , Yanping Huo 1 , Kun Zhang 1
Affiliation  

An efficient allylic C−H phosphorylation has been achieved through the DDQ‐promoted cross‐dehydrogenative coupling of 1,3‐diarylpropenes with P(O)H compounds at room temperature. This method provides a convenient route to allylphosphonates in up to 97% yield with good functional group compatibility.

中文翻译:

DDQ促进1,3-二芳基丙烯的烯丙基CH磷酸化

在室温下,通过DDQ促进1,3-二芳基丙烯与P(O)H化合物的交叉脱氢偶联,实现了有效的烯丙基CH磷酸化。该方法提供了一种方便的途径,以高达97%的产率获得烯丙基膦酸酯,并具有良好的官能团相容性。
更新日期:2018-07-26
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