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Applicability of nonionic surfactant alkyl polyglucoside in preparation of liquid CO2 emulsion
Journal of CO2 Utilization ( IF 7.7 ) Pub Date : 2018-06-18 , DOI: 10.1016/j.jcou.2018.06.005
Hui-Bo Qin , Xiao-Chao Sun , Chang-Yu Sun , Guang-Jin Chen , Zheng-Fu Ning , Ke-Le Yan , Lan-Ying Yang

The essential characteristic of CO2 makes most surfactants futile to form stable CO2 emulsion. In this work, a green surfactant named alkyl polyglucoside (APG) was applied to prepare liquid CO2 emulsion. The performance of surfactant on CO2 emulsion stability was assessed in a sapphire cell by delamination time of emulsion under the operating conditions about 284.5 K and 5.2 MPa. The results demonstrate that APG has a potential to be used in CO2 emulsion preparation and the suitable dosage of APG is about 3.0 wt% water quality. The phase-inversion point of water-in-CO2 and CO2-in-water was determined as ranging from 15 vol% to 17.5 vol% (water cut) after examining the systems at different water cuts with 3.0 wt% APG. Two surfactants, fatty alcohol polyoxyethylene ether (AEO) and sodium bis(2-ethylhexyl) sulfosuccinate (AOT) were also tested. To consider the applicability of CO2 emulsion in fields such as submarine hydrate exploitation and CO2 sequestration, the performance of surfactants in saline solution was examined. The experimental results show that APG can be used as surfactant in preparing liquid CO2 emulsion with or without NaCl. The adding of 1.0 wt% NaCl for CO2 emulsion with 3.0 wt% APG was proved to change the phase-inversion point to higher water cut. In comparison, anion surfactant AOT was futile in saline solution.



中文翻译:

非离子表面活性剂烷基多糖苷在制备液态CO 2乳液中的适用性

CO 2的基本特性使大多数表面活性剂徒劳无功,无法形成稳定的CO 2乳液。在这项工作中,使用一种名为烷基聚葡萄糖苷(APG)的绿色表面活性剂来制备液态CO 2乳液。通过在约284.5 K和5.2 MPa的操作条件下乳化液的分层时间,评估了蓝宝石电池中表面活性剂对CO 2乳化液稳定性的性能。结果表明,APG具有用于CO 2乳液制备的潜力,并且APG的合适剂量为约3.0重量%的水质量。CO 2和CO 2包水的相变点在使用3.0 wt%的APG在不同含水率下检查系统后,确定水中含水率为15体积%至17.5体积%(含水率)。还测试了两种表面活性剂,脂肪醇聚氧乙烯醚(AEO)和双(2-乙基己基)磺基琥珀酸钠(AOT)。为了考虑CO 2乳液在海底水合物开采和CO 2隔离等领域的适用性,研究了盐溶液中表面活性剂的性能。实验结果表明,在有或无NaCl的条件下,APG均可作为表面活性剂用于制备液态CO 2乳液。添加1.0 wt%的NaCl用于CO 2事实证明,具有3.0 wt%APG的乳液可将相转化点改变为更高的含水率。相比之下,阴离子表面活性剂AOT在盐溶液中无效。

更新日期:2018-06-18
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