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Mil-100(Fe) nanoparticles supported on urchin like Bi2S3 structure for improving photocatalytic degradation of rhodamine-B dye under visible light irradiation
Journal of Solid State Chemistry ( IF 3.3 ) Pub Date : 2018-07-05 , DOI: 10.1016/j.jssc.2018.07.006
Soheil Abdpour , Elaheh Kowsari , Mohammad Reza Alavi Moghaddam , Laura Schmolke , Christoph Janiak

Metal organic framework (MOFs) have been attracted a great attention as a new type photocatalysts due to their unique properties. In this work, the new hybrid photocatalyst based on fabrication hybrid structures between MIL-100(Fe) and Bi2S3 (MIL-100(Fe)@Bi2S3) were synthesized via simple hydrothermal method. The photocatalytic degradation of Rhodamine B (RhB) over the as-prepared samples showed that the hybrid photocatalyst samples had higher photocatalytic performance compared to the individual components (MIL-100(Fe) and Bi2S3). The higher photocatalytic performance of the hybrid photocatalysts was proved by electrochemical and photoelectrochemical analysis such as electrochemical impedance spectroscopy (EIS) and also photocurrent measurement. In addition, the possible photocatalytic mechanism based on the optical, photoelectrochemical and quenching tests was proposed.



中文翻译:

像Bi 2 S 3结构一样负载在海胆上的Mil-100(Fe)纳米颗粒,用于改善可见光照射下若丹明-B染料的光催化降解

金属有机骨架(MOFs)由于其独特的性能而作为一种新型的光催化剂受到了广泛的关注。通过简单的水热法合成了基于MIL-100(Fe)和Bi 2 S 3(MIL-100(Fe)@Bi 2 S 3)之间混合结构的新型杂化光催化剂。罗丹明B(RhB)在制备样品上的光催化降解表明,杂化光催化剂样品与单个组分(MIL-100(Fe)和Bi 2 S 3)相比具有更高的光催化性能。)。通过电化学和光电化学分析,例如电化学阻抗谱(EIS)以及光电流测量,证明了杂化光催化剂具有更高的光催化性能。此外,提出了基于光,光电化学和猝灭试验的可能的光催化机理。

更新日期:2018-07-12
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